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Poly[[μ(4)-bis-(4-pyridyl-carbon-yl)piperazine-κN:N':O:O']bis-(thio-cyanato-κN)cobalt(II)].

ABSTRACT: In the title compound, [Co(NCS)(2)(C(16)H(16)N(4)O(2))](n), the octa-hedrally coordinated Co(II) ion lies on a crystallographic inversion center, with trans isothio-cyanate ligands. Pyridyl N-donor atoms and formyl O-donor atoms from exotetra-dentate bis-(4-pyridyl-carbon-yl)piperazine (4-bpfp) ligands link the Co(NCS)(2) units into a [Co(NCS)(2)(4-bpfp)](n) coordination polymer layer that is oriented parallel to (101). The layers stack along [010] to construct the pseudo-three-dimensional structure.

SUBMITTER: Wilseck ZM 

PROVIDER: S-EPMC2979522 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Poly[[μ(4)-bis-(4-pyridyl-carbon-yl)piperazine-κN:N':O:O']bis-(thio-cyanato-κN)cobalt(II)].

Wilseck Zachary M ZM   Laduca Robert L RL  

Acta crystallographica. Section E, Structure reports online 20100529 Pt 6

In the title compound, [Co(NCS)(2)(C(16)H(16)N(4)O(2))](n), the octa-hedrally coordinated Co(II) ion lies on a crystallographic inversion center, with trans isothio-cyanate ligands. Pyridyl N-donor atoms and formyl O-donor atoms from exotetra-dentate bis-(4-pyridyl-carbon-yl)piperazine (4-bpfp) ligands link the Co(NCS)(2) units into a [Co(NCS)(2)(4-bpfp)](n) coordination polymer layer that is oriented parallel to (101). The layers stack along [010] to construct the pseudo-three-dimensional struc  ...[more]

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