Hexakis(dimethyl-ammonium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra-deca-μ(2)-oxido-octa-oxidodeca-vanadate(V) monohydrate.

ABSTRACT: In the title compound, (C(2)H(8)N)(6)[V(10)O(28)]·H(2)O, the [V(10)O(28)](6-) polymetalate anion has crystallographic mirror symmetry with six V atoms and 12 O atoms lying on the mirror plane. Each of the V(V) atoms adopts a distorted octa-hedral geometry. Eight terminal O atoms are bonded to V(V) atoms with double bonds and the others act as bridging atoms. In the crystal structure, a network of N-H⋯O and O-H⋯O hydrogen bonds helps to establish the packing.

SUBMITTER: Wang S 

PROVIDER: S-EPMC2979636 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature