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Catena-Poly[lead(II)-bis-(μ(2)-pyridazine-3-carboxyl-ato-κN,O:O)].

ABSTRACT: In the title structure, [Pb(C(5)H(3)N(2)O(2))(2)](n), the Pb(II) ion is six-coordinated by two pyridazine-3-carboxyl-ate ligands via N and O atoms, with the carboxyl-ato O atoms acting as bidentate and bridging adjacent Pb(II) ions, giving rise to catenated mol-ecular ribbons propagating along the a-axis direction. The ribbons are connected by C-H⋯O hydrogen bonds and van der Waals inter-actions.

SUBMITTER: Starosta W 

PROVIDER: S-EPMC2979802 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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catena-Poly[lead(II)-bis-(μ(2)-pyridazine-3-carboxyl-ato-κN,O:O)].

Starosta Wojciech W   Leciejewicz Janusz J  

Acta crystallographica. Section E, Structure reports online 20100123 Pt 2

In the title structure, [Pb(C(5)H(3)N(2)O(2))(2)](n), the Pb(II) ion is six-coordinated by two pyridazine-3-carboxyl-ate ligands via N and O atoms, with the carboxyl-ato O atoms acting as bidentate and bridging adjacent Pb(II) ions, giving rise to catenated mol-ecular ribbons propagating along the a-axis direction. The ribbons are connected by C-H⋯O hydrogen bonds and van der Waals inter-actions. ...[more]

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