Browse
Submit Data
Databases
API
Help

Dataset Information

53 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis(trimethyl-phenyl-ammonium) tetra-bromidocuprate(II).

ABSTRACT: The crystal structure of the title compound, (C(9)H(14)N)(2)[CuBr(4)], consists of two quarternary ammonium cations and a tetra-hedral cuprate anions. Weak C-H⋯Br hydrogen bonding is present between the cation and anion in the crystal structure.

SUBMITTER: Lo KM

PROVIDER: S-EPMC2979935 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis(trimethyl-phenyl-ammonium) tetra-bromidocuprate(II).

Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100116 Pt 2

The crystal structure of the title compound, (C(9)H(14)N)(2)[CuBr(4)], consists of two quarternary ammonium cations and a tetra-hedral cuprate anions. Weak C-H⋯Br hydrogen bonding is present between the cation and anion in the crystal structure. ...[more]

PMID: 21579641

Similar Datasets

Bis(benzyl-trimethyl-ammonium) tetra-bromidocuprate(II).

Project description:In the title mol-ecular salt, (C(10)H(16)N)(2)[CuBr(4)], the Cu(II) ion adopts a squashed tetra-hedral geometry with Br-Cu-Br angles varying between 99.29 (3) and 132.53 (3)°. In the crystal, the components are linked by C-H⋯Br inter-actions, thereby generating a three-dimensional network.

| S-EPMC3200753 | biostudies-literature

Bis(diallyl-benzimidazolium) tetra-bromidocuprate(II).

Project description:The structure of the title ionic copper(II) compound, (C(13)H(15)N(2))(2)[CuBr(4)], is built up of isolated 1,3-diallyl-benzimidazolium cations and [CuBr(4)](2-) anions which are inter-connected by electrostatic inter-actions. Differences in packing of the heterocyclic cores results in a different structure compared with earlier investigated chloride and bromide analogues.

| S-EPMC2961985 | biostudies-literature

Bis(trimethyl-phenyl-ammonium) tetra-bromidobis(4-chloro-phen-yl)stannate(IV).

Project description:The Sn(IV) atom in the title salt, [N(CH(3))(3)(C(6)H(5))](2)[SnBr(4)(C(6)H(4)Cl)(2)], exists in a distorted all-trans SnC(2)Br(4) octa-hedral geometry. The Sn(IV) atom lies on a center of inversion. Weak inter-molecular C-H⋯Br hydrogen bonding is observed between trimethyl-phenyl-ammonium cations and the Sn complex anion in the crystal structure.

| S-EPMC2971998 | biostudies-literature

Bis(2-phenyl-ethyl-ammonium) tetra-chloridocobaltate(II).

Project description:Crystals of the title compound, (C(6)H(5)CH(2)CH(2)NH(3))(2)[CoCl(4)], were grown by the solvent-evaporation method. This inorganic-organic hybrid compound exhibits a layered structure in which isolated CoCl(4) inorganic layers alternate with bilayers of phenylethylammonium cations. Although the inorganic anion is zero-dimensional, the layered structure is stabilized via N-H⋯Cl hydrogen bonds. The CoCl(4) tetra-hedra connect to the cations through N-H⋯Cl hydrogen bonds, building a two-dimensional network extending parallel to (010).

| S-EPMC3089155 | biostudies-literature

Bis[4-(dimethyl-amino)pyridinium] tetra-bromidocuprate(II).

Project description:The metal atom in the anion of the title salt, (C(7)H(11)N(2))(2)[CuBr(4)], shows a distorted tetra-hedral coordination. The primary contacts between the ions are of the N-H⋯Br type.

| S-EPMC2977401 | biostudies-literature

Bis(1-methyl-piperazine-1,4-diium) tetra-bromidocuprate(II).

Project description:The title compound, (C(5)H(14)N(2))[CuBr(4)], was synthesized by hydro-thermal reaction of CuBr(2) with 1-methyl-piperazine in an HBr/water solution. Both amine N atoms are protonated. The Cu-Br distances in the tetrahedral anion are in the range 2.3809 (11)-2.4131 (11) Å. In the crystal, moderately strong and weak inter-molecular N-H⋯Br hydrogen bonds link the anion and cation units into an infinite two-dimensional network parallel to the ab plane.

| S-EPMC3151897 | biostudies-literature

Bis(trimethyl-ammonium) tetra-chlorido-diphenyl-stannate(IV).

Project description:The title compound, [(CH(3))(3)NH](2)[Sn(C(6)H(5))(2)Cl(4)], consists of [(CH(3))(3)NH](+) cations and [SnPh(2)Cl(4)](2-) anions in which the Sn atom, located on a centre of inversion, is bonded to four Cl atoms and two phenyl rings, giving an octa-hedral geometry with the phenyl rings in trans positions. In the crystal, the cations and the anions are connected by N-H⋯Cl hydrogen bonds and C-H⋯Cl inter-actions.

| S-EPMC3051760 | biostudies-literature

Bis(trimethyl-phenyl-ammonium) μ-oxalato-bis-[oxidodiperoxido-molybdate(VI)].

Project description:A trimethyl-phenyl-ammonium salt of a dinuclear μ-oxalate complex of diperoxidomonomolybdate units, (C9H14N)2[Mo2(C2O4)(O2)4O2], was obtained from an acidic aqueous solution; the dianion is located about a centre of inversion. Each Mo atom bears two peroxide groups together with one O atom from the oxalate group in its equatorial positions and one terminal O atom as well as another O atom from the oxalate in axial positions. The oxalate group acts as a tetra-dentate bridging ligand and bridges between the diperoxidomolybdate units.

| S-EPMC3588729 | biostudies-literature

Bis(diisopropyl-ammonium) tetra-chloridocuprate(II).

Project description:In the title mol-ecular salt, (C(6)H(16)N)(2)[CuCl(4)], the Cu(II) ion adopts an extremely distorted tetra-hedral coordination geometry. All the ammonium H atoms are involved in N-H⋯Cl hydrogen bonds, which serve to link the cations and anions into chains propagating along the c-axis direction.

| S-EPMC3297241 | biostudies-literature

Bis(benzyl-trimethyl-ammonium) di-μ-bromido-bis-[dibromido-mercurate(II)].

Project description:In the crystal structure of the title compound, (C(10)H(16)N)(2)[Hg(2)Br(6)], the condensed anion consists of two edge-sharing HgBr(4) tetrahedra and is situated on a centre of symmetry. The anions are linked to the cations through weak C-H⋯Br inter-actions.

| S-EPMC3274863 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data