Poly[[(N,N-dimethyl-formamide-κO)(μ(3)-pyrazine-2,3-dicarboxyl-ato-κN,O:O:O)copper(II)] monohydrate].

ABSTRACT: In the title compound, {[Cu(C(6)H(2)N(2)O(4))(C(3)H(7)NO)]·H(2)O}(n), the Cu(II) atom is coordinated by an N,O-bidentate pyrazine-2,3-dicarboxyl-ate (pzdc) dianion, two O atoms from two other pzdc anions and one O atom from the dimethlyformamide ligand, forming a distorted square-pyramidal CuNO(4) geometry. The polymeric character of the structure is established by the formation of layers parallel to (100) via bridging pzdc ligands. O-H⋯O hydrogen bonding between water mol-ecules and uncoordinated carboxyl-ate O atoms leads to additional stabilization of the structure.

SUBMITTER: Fan ZZ 

PROVIDER: S-EPMC2979988 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature