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[(2-Pyrid-yl)methanol-κN,O]bis-(thio-cyanato-κN)manganese(II).

ABSTRACT: In the title complex, [Mn(NCS)(2)(C(6)H(7)NO)(2)], the Mn(II) atom shows site symmetry 2. The distorted octa-hedral environment of Mn(II) is defined by two N atoms [Mn-N = 2.217 (4) and 2.132 (5) Å] and one O atom [Mn-O 2.305 (4) Å]. There are inter-molecular O-H⋯S hydrogen bonds and inter-molecular π-π stacking inter-actions between adjacent (2-pyrid-yl)methano-late ligands [centroid-centroid distance = 3.5569 (7) Å], leading to a chain structure running along [100].

SUBMITTER: Gao Q

PROVIDER: S-EPMC2983231 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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[(2-Pyrid-yl)methanol-κN,O]bis-(thio-cyanato-κN)manganese(II).

Gao Qihe Q Bao Qianqian Q Rong Rong R

Acta crystallographica. Section E, Structure reports online 20100904 Pt 10

In the title complex, [Mn(NCS)(2)(C(6)H(7)NO)(2)], the Mn(II) atom shows site symmetry 2. The distorted octa-hedral environment of Mn(II) is defined by two N atoms [Mn-N = 2.217 (4) and 2.132 (5) Å] and one O atom [Mn-O 2.305 (4) Å]. There are inter-molecular O-H⋯S hydrogen bonds and inter-molecular π-π stacking inter-actions between adjacent (2-pyrid-yl)methano-late ligands [centroid-centroid distance = 3.5569 (7) Å], leading to a chain structure running along [100]. ...[more]

PMID: 21587362

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{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N'',N'''}bis-(thio-cyanato-κN)manganese(II).

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