Tetra-aqua-bis{μ(2)-2,7-bis-[(2,6-diisopropyl-phen-yl)imino-meth-yl]naphthalene-1,8-diolato}di-μ(3)-hydroxido-di-μ(2)-hydroxido-bis-(trimethyl-phosphine oxide)tetra-nickel(II)-trimethyl-phosphine oxide-diethyl ether-water (1/2/2/2).

ABSTRACT: The title complex, [Ni(4)(C(36)H(40)N(2)O(2))(2)(OH)(4)(C(3)H(9)OP)(2)(H(2)O)(4)]·2C(4)H(10)O·2C(3)H(9)OP·2H(2)O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each Ni(II) atom adopts a distorted octa-hedral geometry.

SUBMITTER: Delferro M 

PROVIDER: S-EPMC2983651 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature