[(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

ABSTRACT: Two independent mol-ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo-hexyl groups as well as the benzene ring. In each mol-ecule, the Au atom is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10 (5) and 177.26 (5)° for the two mol-ecules], with the distortion due in part to the close intra-molecular approach of the O atom [Au⋯O contacts = 3.054 (4) and 3.013 (4) Å, respectively, for the two mol-ecules].

SUBMITTER: Tadbuppa PP 

PROVIDER: S-EPMC2983779 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature