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Tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxy-ethyl]carbamate.

ABSTRACT: In the title compound, C(8)H(17)N(3)O(4), the dihedral angle between the hydrazinecarbonyl and carbamate groups is 44.94 (12)°, and the carbonyl groups are anti to each other. In the crystal, the hydr-oxy group forms an O-H⋯N(a) (a = amine) hydrogen bond and each of the four N-H atoms forms an N-H⋯O hydrogen bond; the hydrazinecarbonyl O atom accepts two such bonds. This results in two-dimensional arrays in the ab plane, mediated by the hydrogen bonding, sandwiched by tert-butyl groups.

SUBMITTER: Pinheiro AC 

PROVIDER: S-EPMC2983938 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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tert-Butyl N-[(S)-1-hydrazinecarbonyl-2-hydroxy-ethyl]carbamate.

Pinheiro Alessandra C AC   de Souza Marcus V N MV   Wardell Solange M S V SM   Wardell James L JL   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20100331 Pt 4

In the title compound, C(8)H(17)N(3)O(4), the dihedral angle between the hydrazinecarbonyl and carbamate groups is 44.94 (12)°, and the carbonyl groups are anti to each other. In the crystal, the hydr-oxy group forms an O-H⋯N(a) (a = amine) hydrogen bond and each of the four N-H atoms forms an N-H⋯O hydrogen bond; the hydrazinecarbonyl O atom accepts two such bonds. This results in two-dimensional arrays in the ab plane, mediated by the hydrogen bonding, sandwiched by tert-butyl groups. ...[more]

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