Backbone tuning in indenylidene-ruthenium complexes bearing an unsaturated N-heterocyclic carbene.

ABSTRACT: The steric and electronic influence of backbone substitution in IMes-based (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) N-heterocyclic carbenes (NHC) was probed by synthesizing the [RhCl(CO)₂(NHC)] series of complexes to quantify experimentally the Tolman electronic parameter (electronic) and the percent buried volume (%V(bur), steric) parameters. The corresponding ruthenium-indenylidene complexes were also synthesized and tested in benchmark metathesis transformations to establish possible correlations between reactivity and NHC electronic and steric parameters.

SUBMITTER: Urbina-Blanco CA 

PROVIDER: S-EPMC3002078 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature