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Pyrrolo-[2,1-c][1,4]benzodiazepine-5,11-dithione.

ABSTRACT: The seven-membered fused-ring in the title compound, C(12)H(12)N(2)S(2), adopts a boat conformation (with the two phenyl-ene C atoms representing the stern and the methine C atom the prow). This methine C atom and the tertiary N atom also belong to a five-membered ring, which has an envelope conformation. In the crystal structure, mol-ecules are linked about a center of inversion by pairs of N-H⋯S hydrogen bonds.

SUBMITTER: Ourahou S

PROVIDER: S-EPMC3006926 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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Pyrrolo-[2,1-c][1,4]benzodiazepine-5,11-dithione.

Ourahou Sarah S Zouihri Hafid H Essassi El Mokhtar el M Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100616 Pt 7

The seven-membered fused-ring in the title compound, C(12)H(12)N(2)S(2), adopts a boat conformation (with the two phenyl-ene C atoms representing the stern and the methine C atom the prow). This methine C atom and the tertiary N atom also belong to a five-membered ring, which has an envelope conformation. In the crystal structure, mol-ecules are linked about a center of inversion by pairs of N-H⋯S hydrogen bonds. ...[more]

PMID: 21587881

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