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Tetra-carbonyl-1κC,3κC-bis[1,3(η)-cyclo-penta-dien-yl]dihydroxido-2κO-diirontin(2 Fe-Sn) monohydrate.

ABSTRACT: In the title hydrate, [Fe(2)Sn(C(5)H(5))(2)(OH)(2)(CO)(4)]·H(2)O, the central Sn atom is tetra-hedrally coordinated by two {Cp(CO)(2)Fe} fragments and two hydroxide groups. The [{Cp(CO)(2)Fe}(2)Sn(OH)(2)] and water mol-ecules are linked by O-H⋯O hydrogen bridges, giving two-dimensional arrays with 4.8(2) topology that stack along the c axis.

SUBMITTER: Kossel S

PROVIDER: S-EPMC3006954 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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Tetra-carbonyl-1κC,3κC-bis[1,3(η)-cyclo-penta-dien-yl]dihydroxido-2κO-diirontin(2 Fe-Sn) monohydrate.

Kössel Stefanie S Wagner Christoph C Merzweiler Kurt K

Acta crystallographica. Section E, Structure reports online 20100618 Pt 7

In the title hydrate, [Fe(2)Sn(C(5)H(5))(2)(OH)(2)(CO)(4)]·H(2)O, the central Sn atom is tetra-hedrally coordinated by two {Cp(CO)(2)Fe} fragments and two hydroxide groups. The [{Cp(CO)(2)Fe}(2)Sn(OH)(2)] and water mol-ecules are linked by O-H⋯O hydrogen bridges, giving two-dimensional arrays with 4.8(2) topology that stack along the c axis. ...[more]

PMID: 21587729

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