Unknown

Dataset Information

0

Trichodermin (12,13-ep-oxy-trichethec-9-en-4?-yl 4-fluoro-benzoate).

ABSTRACT: IN THE TITLE TRICHODERMIN COMPOUND (SYSTEMATIC NAME: 12,13-ep-oxy-trichothec-9-en-4?-yl 4-fluoro-benzoate), C(22)H(25)FO(4), the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the different conformations, viz. chair and half-chair. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 68.67?(2)°; these two mean planes are nearly perpendicular to the ep-oxy ring with angles of 87.97?(2)and 88.14?(2)°, respectively.

SUBMITTER: Xu XH 

PROVIDER: S-EPMC3007378 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Trichodermin (12,13-ep-oxy-trichethec-9-en-4β-yl 4-fluoro-benzoate).

Xu Xu-Hui XH   Wang Zong-Cheng ZC   Cheng Jing-Li JL   Zhou Yong Y   Zhao Jin-Hao JH  

Acta crystallographica. Section E, Structure reports online 20100724 Pt 8

IN THE TITLE TRICHODERMIN COMPOUND (SYSTEMATIC NAME: 12,13-ep-oxy-trichothec-9-en-4β-yl 4-fluoro-benzoate), C(22)H(25)FO(4), the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the different conformations, viz. chair and half-chair. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 68.67 (2)°; these two mean planes are  ...[more]

Similar Datasets

Unknown Trichodermin (4β-acet-oxy-12,13-epoxy-trichothec-9-ene).
| S-EPMC2960951 | biostudies-literature
Unknown 8-{[(E)-3-(2-Chloro-phen-yl)acrylo-yloxy]imino}-12,13-ep-oxy-trichethec-9-en-4-yl (E)-3-(2-chloro-phen-yl)acrylate.
| S-EPMC3247573 | biostudies-literature
Unknown Dihalogenated trichodermin (4?-acet-oxy-9,10-dibromo-12,13-epoxy-tri-chothec).
| S-EPMC2980171 | biostudies-literature
Unknown 4?-Hy-droxy-12,13-ep-oxy-trichothec-9-ene.
| S-EPMC3344132 | biostudies-literature
Unknown 4-Cyano-3-fluoro-phenyl 4-(hexa-dec-yl-oxy)benzoate.
| S-EPMC3998482 | biostudies-literature
Unknown 2-Meth-oxy-4-(prop-2-en-1-yl)phenyl benzoate.
| S-EPMC3770366 | biostudies-literature
Unknown 16?,17?-Ep-oxy-17?-(1H-imidazol-1-yl)androst-4-en-3-one monohydrate.
| S-EPMC3414280 | biostudies-literature
Unknown 2-Meth-oxy-4-(prop-2-en-1-yl)phenyl 2,4-di-chloro-benzoate.
| S-EPMC3770367 | biostudies-literature
Unknown 1-(2-Fluoro-phen-yl)-3-(2,4,6-trimeth-oxy-phen-yl)prop-2-en-1-one.
| S-EPMC3515281 | biostudies-literature
Unknown 1,3-Phenyl-ene bis-{3-[2-chloro-4-(tri-fluoro-meth-yl)phen-oxy]benzoate}.
| S-EPMC3414352 | biostudies-literature