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(OC-6-33)-(2,2'-Bipyridine-?N,N')trimeth-yl(2-methyl-sulfanyl-2-thia-zoline-?N)platinum(IV) tetra-fluoridoborate.

ABSTRACT: The asymmetric unit of the title complex, [Pt(CH(3))(3)(C(10)H(8)N(2))(C(4)H(7)NS(2))]BF(4), contains two crystallographically independent mol-ecules. The Pt(IV) atom in each complex cation exhibits a distorted octa-hedral coordination geometry, built up by three methyl ligands in a facial binding fashion, a bipyridine ligand and a monodentately N-bound 2-methyl-sulfanyl-2-thia-zoline ligand (configuration index: OC-6-33). In the crystal structure, weak inter-molecular C-H?F hydrogen bonds are found between the complex cations and BF(4) (-) anions.

SUBMITTER: Vetter C

PROVIDER: S-EPMC3007407 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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(OC-6-33)-(2,2'-Bipyridine-κN,N')trimeth-yl(2-methyl-sulfanyl-2-thia-zoline-κN)platinum(IV) tetra-fluoridoborate.

Vetter Cornelia C Bruhn Clemens C Steinborn Dirk D

Acta crystallographica. Section E, Structure reports online 20100717 Pt 8

The asymmetric unit of the title complex, [Pt(CH(3))(3)(C(10)H(8)N(2))(C(4)H(7)NS(2))]BF(4), contains two crystallographically independent mol-ecules. The Pt(IV) atom in each complex cation exhibits a distorted octa-hedral coordination geometry, built up by three methyl ligands in a facial binding fashion, a bipyridine ligand and a monodentately N-bound 2-methyl-sulfanyl-2-thia-zoline ligand (configuration index: OC-6-33). In the crystal structure, weak inter-molecular C-H⋯F hydrogen bonds are f ...[more]

PMID: 21588173

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