Catena-Poly[[tris-(4-fluoro-benz-yl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothio-ylsulfan-yl]acetato-κO:O'].

ABSTRACT: Adjacent units of the title polymeric complex, [Sn(C(7)H(6)F)(3)(C(8)H(12)NO(2)S(2))], are bridged by the carboxyl-ate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C(3)SnO(2) trigonal-bipyramidal coordination and is displaced by 0.113 (2) Å out of the C(3)Sn girdle in the direction of the covalently bonded O atom. The ring is disordered of two positions with an occupancy of 0.631 (4) for the major occupied site.

SUBMITTER: Keng CT 

PROVIDER: S-EPMC3007486 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature