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KPr(PO(3))(4).

ABSTRACT: Single crystals of the title compound, potassium praseodymium(III) polyphosphate, were obtained by solid-state reaction. The monoclinic non-centrosymmetric structure is isotypic with all other KLn(PO(3))(4) analogues from Ln = La to Er, inclusive. The crystal structure of these long-chain polyphosphates is built up from infinite crenelated polyphosphate chains of corner-sharing PO(4) tetra-hedra with a repeating unit of four tetra-hedra. These chains, running along [100], are arranged in a pseudo-tetra-gonal rod packing and are further linked by isolated PrO(8) square anti-prisms [Pr-O = 2.3787?(9)-2.5091?(8)?Å], forming a three-dimensional framework. The K(+) ions reside in channels parallel to [010] and exhibit a highly distorted coordination sphere by eight O atoms at distances ranging from 2.7908?(9) to 3.1924?(11)?Å.

SUBMITTER: Oudahmane A 

PROVIDER: S-EPMC3007571 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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KPr(PO(3))(4).

Oudahmane Abdelghani A   Daoud Mohamed M   Tanouti Boumediene B   Avignant Daniel D   Zambon Daniel D  

Acta crystallographica. Section E, Structure reports online 20100714 Pt 8

Single crystals of the title compound, potassium praseodymium(III) polyphosphate, were obtained by solid-state reaction. The monoclinic non-centrosymmetric structure is isotypic with all other KLn(PO(3))(4) analogues from Ln = La to Er, inclusive. The crystal structure of these long-chain polyphosphates is built up from infinite crenelated polyphosphate chains of corner-sharing PO(4) tetra-hedra with a repeating unit of four tetra-hedra. These chains, running along [100], are arranged in a pseud  ...[more]