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4-Meth-oxy-benzaldehyde (5-bromo-pyrimidin-2-yl)hydrazone monohydrate.

ABSTRACT: In the title Schiff base compound, C(12)H(11)BrN(4)O·H(2)O, the organic mol-ecule exists in an E configuration with respect to the C=N double bond. The pyrimidine ring is approximately planar, with a maximum deviation of 0.011 (2) Å, and forms a dihedral angle of 10.68 (8)° with the benzene ring. In the crystal, inter-molecular O-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into a two-dimensional network parallel to the ac plane.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3007892 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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4-Meth-oxy-benzaldehyde (5-bromo-pyrimidin-2-yl)hydrazone monohydrate.

Fun Hoong-Kun HK Loh Wan-Sin WS Nayak Suresh P SP

Acta crystallographica. Section E, Structure reports online 20100828 Pt 9

In the title Schiff base compound, C(12)H(11)BrN(4)O·H(2)O, the organic mol-ecule exists in an E configuration with respect to the C=N double bond. The pyrimidine ring is approximately planar, with a maximum deviation of 0.011 (2) Å, and forms a dihedral angle of 10.68 (8)° with the benzene ring. In the crystal, inter-molecular O-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into a two-dimensional network parallel to the ac plane. ...[more]

PMID: 21588785

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