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Aqua-chlorido{2-[2-(cyclo-hexyl-carbamo-thioyl-κS)hydrazinyl-idene-κN]propano-ato(2-)}phenyl-tin(IV).

ABSTRACT: In the title organotin compound, [Sn(C(6)H(5))(C(10)H(15)N(3)O(2)S)Cl(H(2)O)], the Sn atom is coordinated by the S, O, and imine N atoms of the dinegative tridentate ligand, a chloride ligand, the ipso-C atom of a phenyl ligand and by a water mol-ecule in a distorted octa-hedral coordination environment. Coordin-ated water mol-ecules link the organotin mol-ecules by forming O-H⋯O hydrogen bonds with both carbonyl and carboxyl-ate O atoms, leading to 12-membered {⋯OCO⋯HOH⋯}(2) synthons. This results in the formation of supra-molecular chains along the c axis. The chains pack in the ac plane and stack along the b axis with links between layers afforded by N-H⋯Cl hydrogen bonds.

SUBMITTER: Affan MA 

PROVIDER: S-EPMC3007908 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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Aqua-chlorido{2-[2-(cyclo-hexyl-carbamo-thioyl-κS)hydrazinyl-idene-κN]propano-ato(2-)}phenyl-tin(IV).

Affan Md Abu MA   Salam Md Abdus MA   Jusoh Ismail I   Ng Seik Weng SW   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20100818 Pt 9

In the title organotin compound, [Sn(C(6)H(5))(C(10)H(15)N(3)O(2)S)Cl(H(2)O)], the Sn atom is coordinated by the S, O, and imine N atoms of the dinegative tridentate ligand, a chloride ligand, the ipso-C atom of a phenyl ligand and by a water mol-ecule in a distorted octa-hedral coordination environment. Coordin-ated water mol-ecules link the organotin mol-ecules by forming O-H⋯O hydrogen bonds with both carbonyl and carboxyl-ate O atoms, leading to 12-membered {⋯OCO⋯HOH⋯}(2) synthons. This resu  ...[more]

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