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Bis[4-(4-chloro-benzo-yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κO,O']bis-(methanol-κO)nickel(II).

ABSTRACT: The mol-ecular structure of the neutral mononuclear title complex, [Ni(C(17)H(12)ClN(2)O(2))(2)(CH(3)OH)(2)], is centrosymmetric. The Ni(II) atom, which is located on an inversion center, is in a distorted octahedral coordination, defined by four O atoms from two ligands as well as two O atoms from two methanol mol-ecules. Inter-molecular O-H⋯N hydrogen bonds between the hy-droxy group of methanol and a pyrazole N atom link the mol-ecules, forming a two-dimensional network parallel to (100).

SUBMITTER: Zhang X

PROVIDER: S-EPMC3008993 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Bis[4-(4-chloro-benzo-yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κO,O']bis-(methanol-κO)nickel(II).

Zhang Xin X Huang Meng M Du Cong C Han Junjing J

Acta crystallographica. Section E, Structure reports online 20101009 Pt 11

The mol-ecular structure of the neutral mononuclear title complex, [Ni(C(17)H(12)ClN(2)O(2))(2)(CH(3)OH)(2)], is centrosymmetric. The Ni(II) atom, which is located on an inversion center, is in a distorted octahedral coordination, defined by four O atoms from two ligands as well as two O atoms from two methanol mol-ecules. Inter-molecular O-H⋯N hydrogen bonds between the hy-droxy group of methanol and a pyrazole N atom link the mol-ecules, forming a two-dimensional network parallel to (100). ...[more]

PMID: 21588804

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