(Ethanolato)[2,3,7,8,12,13,17,18-octa-ethylporphyrinato(2-)]iron(III).

ABSTRACT: The title compound, [Fe(C(2)H(5)O)(C(36)H(44)N(4))], contains a five-coordinate iron-porphyrin complex with an axial eth-oxy ligand. The iron(III) atom is displaced by 0.504 (2) Å towards the eth-oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe-N(p) distance is 2.078 (2) Å and the Fe-O distance is 1.8232 (18) Å. The eth-oxy C atoms are disordered in a 0.581 (12):0.419 (12) ratio. The bond angles of the Fe-O-C linkage are 128.6 (3) and 130.4 (3)°, respectively, for the major and minor occupancy C atoms.

SUBMITTER: Cheng L 

PROVIDER: S-EPMC3009112 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature