Stereoselective 6π-electron electrocyclic ring closures of 2-halo-amidotrienes via a remote 1,6-asymmetric induction.

ABSTRACT: A diastereoselective 6π-electrocyclic ring closure employing halogen-substituted 3-amidotrienes via a 1,6-remote asymmetric induction is described. This new asymmetric manifold for pericyclic ring closure further underscores the significance of the allenamide chemistry.

SUBMITTER: Hayashi R 

PROVIDER: S-EPMC3010762 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature