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Dataset Information

Azido-{2-[bis-(2-hy-droxy-eth-yl)amino]-ethano-lato-κN,O,O',O''}cobalt(II).


ABSTRACT: In the title complex, [Co(C(6)H(14)NO(3))(N(3))] or [Co(teaH(2))N(3)], the Co(II) atom resides in a trigonal-bipymidal O(3)N(2) environment formed by three O atoms and one N atom from a simply deprotonated tetra-dentate triethano-lamine ligand, and one N atom from an azide ligand. The O atoms define the equatorial plane whereas both N atoms are in axial positions. The mononuclear units are linked through O-H⋯O hydrogen-bonding inter-actions between the ethanol OH groups and the ethano-late O atom of a neighbouring complex into chains running parallel to [010].

SUBMITTER: Liu YJ 

PROVIDER: S-EPMC3011546 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature