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Bis(2,2'-bipyridine-?N,N')dichloridocadmium(II).

ABSTRACT: The Cd(II) atom in the title compound, [CdCl(2)(C(10)H(8)N(2))(2)] exists in a distorted octa-hedral geometry [N-Cd-N = 148.29?(17)°]; the Cl atoms are cis with respect to each other.

SUBMITTER: Gao S

PROVIDER: S-EPMC3011694 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Bis(2,2'-bipyridine-κN,N')dichloridocadmium(II).

Gao Shan S Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20101130 Pt 12

The Cd(II) atom in the title compound, [CdCl(2)(C(10)H(8)N(2))(2)] exists in a distorted octa-hedral geometry [N-Cd-N = 148.29 (17)°]; the Cl atoms are cis with respect to each other. ...[more]

PMID: 21589347

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Bis(2,2'-bipyridine-κN,N')dibromido-cadmium(II).

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Bis(2,2'-bipyridine-κN,N')chloridocobalt(II) perchlorate.

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Project description:The asymmetric unit of title compound, [Cu(NCS)(C(10)H(8)N(2))(2)]ClO(4), contains a bis-(2,2'-bipyridine)(isothio-cyanato)copper(II) cation and a perchlorate anion. In the cation, the Cu(2+) ion is coordinated by four N atoms from two bidentate 2,2'-bipyridine mol-ecules and an N atom from an isothio-cyanate anion, resulting in a distorted CuN(5) pyramidal configuration. The crystal structure is stabilized by weak inter-molecular C-H⋯O and C-H⋯S hydrogen bonds, and weak π-π inter-actions between 2,2'-bipyridine rings [centroid-centroid distance = 3.908 (4) Å]. The perchlorate counteranion is disordered over two positions in a 0.66:0.34 ratio.

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