(C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-4,11-diene)copper(II) bis-[O,O'-bis-(4-methyl-phen-yl)dithio-phosphate].

ABSTRACT: In the title compound, [Cu(C(24)H(32)N(4))](C(14)H(14)O(2)PS(2))(2), the Cu(II) atom lies on an inversion center and is chelated by the macrocyclic ligand in a distorted CuN(4) square-planar geometry. Two O,O'-bis-(4-methyl-phen-yl)dithio-phosphate anions occupy the axial positions with long Cu⋯S distances of 3.0090 (8) Å. Inter-molecular N-H⋯S and C-H⋯S hydrogen bonding is present between the anions and the cation.

SUBMITTER: Zou LK 

PROVIDER: S-EPMC3011789 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature