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Palladium-catalyzed 1,1-aryloxygenation of terminal olefins.


ABSTRACT: This paper describes the 1,1-arylacetoxylation of diverse α-olefins using organostannanes and hypervalent iodine oxidants. The reaction provides a convergent approach for generating a C-C and a C-O bond as well as a new stereocenter in a single catalytic transformation.

SUBMITTER: Satterfield AD 

PROVIDER: S-EPMC3047416 | biostudies-literature | 2011 Mar

REPOSITORIES: biostudies-literature