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N,N,N',N'-Tetra-methyl-ethylene-diammonium tetra-chloridocobaltate(II).


ABSTRACT: The asymmetric unit of the title compound, [(CH(3))(2)NH(CH(2))(2)NH(CH(3))(2)][CoCl(4)], contains a tetra-chlorido-cobalt-ate(II) dianion and two halves of two centrosymmetric, crystallographically-independent, dications. One independent dication is disordered between two conformations in a 0.784 (13):0.216 (13) ratio. In the crystal, inter-molecular N-H⋯Cl hydrogen bonds link cations and anions into chains propagated in [01]. These hydrogen bonds contribute to the distorted tetra-hedral geometry at the Co(II) atom.

SUBMITTER: Baughman RG 

PROVIDER: S-EPMC3050123 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature