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Al(0.5)Nb(1.5)(PO(4))(3).

ABSTRACT: Single crystals of the title compound, aluminium niobium triphosphate, Al(0.5)Nb(1.5)(PO(4))(3), have been synthesized by a high-temperature reaction in a platinium crucible. The Al(III) and Nb(V) atoms occupy the same site on the axis, with disorder in the ratio of 1:3. The fundamental building units of the title structure are isolated Al/NbO(6) octa-hedra and PO(4) tetra-hedra (. 2 symmetry), which are further inter-locked by corner-sharing O atoms, leading to a three-dimensional framework structure with infinite channels along the a axis.

SUBMITTER: Zhao D 

PROVIDER: S-EPMC3051931 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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Al(0.5)Nb(1.5)(PO(4))(3).

Zhao Dan D   Liang Peng P   Su Ling L   Chang Huan H   Yan Shi S  

Acta crystallographica. Section E, Structure reports online 20110212 Pt 3

Single crystals of the title compound, aluminium niobium triphosphate, Al(0.5)Nb(1.5)(PO(4))(3), have been synthesized by a high-temperature reaction in a platinium crucible. The Al(III) and Nb(V) atoms occupy the same site on the axis, with disorder in the ratio of 1:3. The fundamental building units of the title structure are isolated Al/NbO(6) octa-hedra and PO(4) tetra-hedra (. 2 symmetry), which are further inter-locked by corner-sharing O atoms, leading to a three-dimensional framework str  ...[more]

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