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(N-Benzyl-N-ethyl-dithio-carbamato)di-tert-butyl-chloridotin(IV).

ABSTRACT: The Sn(IV) atom in the title diorganotin dithio-carbamate, [Sn(C(4)H(9))(2)Cl(C(10)H(12)NS(2))], is penta-coordinated by an asymmetrically coordinating dithio-carbamate ligand, a Cl and two C atoms of the Sn-bound tert-butyl groups. The resulting C(2)ClS(2) donor set defines a coordination geometry inter-mediate between square pyramidal and trigonal bipyramidal with a slight tendency towards the former. In the crystal structure, C-H⋯π contacts link centrosymmetrically related mol-ecules into dimeric aggregates.

SUBMITTER: Abdul Muthalib AF

PROVIDER: S-EPMC3051941 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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(N-Benzyl-N-ethyl-dithio-carbamato)di-tert-butyl-chloridotin(IV).

Abdul Muthalib Amirah Faizah AF Baba Ibrahim I Mohamed Tahir Mohamed Ibrahim MI Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20110226 Pt 3

The Sn(IV) atom in the title diorganotin dithio-carbamate, [Sn(C(4)H(9))(2)Cl(C(10)H(12)NS(2))], is penta-coordinated by an asymmetrically coordinating dithio-carbamate ligand, a Cl and two C atoms of the Sn-bound tert-butyl groups. The resulting C(2)ClS(2) donor set defines a coordination geometry inter-mediate between square pyramidal and trigonal bipyramidal with a slight tendency towards the former. In the crystal structure, C-H⋯π contacts link centrosymmetrically related mol-ecules into dim ...[more]

PMID: 21522295

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