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(S)-1-(2-Chloro-phen-yl)-2-oxocyclo-hexan-1-aminium d-tartrate.

ABSTRACT: In the title compound, C(12)H(15)ClNO(+)·C(4)H(5)O(6) (-), the cyclo-hexa-none ring adopts a chair conformation. The benzene ring is significantly twisted so that it is in an almost perpendicular position to the C-N bond with a C(Ar)-C(Ar)-C-N torsion angle of -96.5 (5)°. Intermolecular N-H⋯O and O-H⋯O hydrogen bonds are observed in the crystal structure.

SUBMITTER: Hojahmat M

PROVIDER: S-EPMC3051988 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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(S)-1-(2-Chloro-phen-yl)-2-oxocyclo-hexan-1-aminium d-tartrate.

Hojahmat Marhaba M Zheng Guangrong G Siegler Max M Parkin Sean S Biermann Manfred M Crooks Peter A PA

Acta crystallographica. Section E, Structure reports online 20110226 Pt 3

In the title compound, C(12)H(15)ClNO(+)·C(4)H(5)O(6) (-), the cyclo-hexa-none ring adopts a chair conformation. The benzene ring is significantly twisted so that it is in an almost perpendicular position to the C-N bond with a C(Ar)-C(Ar)-C-N torsion angle of -96.5 (5)°. Intermolecular N-H⋯O and O-H⋯O hydrogen bonds are observed in the crystal structure. ...[more]

PMID: 21522475

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