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A short asymmetric route to the bromophycolide A and D skeleton.


ABSTRACT: An asymmetric synthesis of the bromophycolide D ring system has been achieved in seven steps from a known geranylgeranylated benzoate, via bromonium-promoted transannular cyclization of a macrocyclic intermediate.

SUBMITTER: Lin H 

PROVIDER: S-EPMC3065244 | biostudies-literature | 2011 Mar

REPOSITORIES: biostudies-literature