Large-scale synthesis of all stereoisomers of a 2,3-unsaturated C-glycoside scaffold.

ABSTRACT: All stereoisomers of a highly functionalized 2,3-unsaturated C-glycoside can be accessed in 10-100 g quantities from readily available starting materials and reagents in 3-7 steps. These chiral scaffolds contain three stereogenic centers along with orthogonally protected functional groups for downstream reactivity.

SUBMITTER: Gerard B 

PROVIDER: S-EPMC3073442 | biostudies-literature | 2011 Mar

REPOSITORIES: biostudies-literature