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Rac-12,14-Dicyclo-propyl-5,8,13,18,21-penta-oxapenta-cyclo-[13.8.0.0.0.0]tricosa-1(15),2(11),3,9(10),16,22(23)-hexa-ene.

ABSTRACT: The mol-ecule of the title compound, C(24)H(24)O(5), has crystallographic twofold symmetry, with the central O atom lying on the rotation axis. The dihedral angle between the best planes of the benzene rings fused to the oxepine fragment is 38.5 (1)°. The dioxine ring adopts a twist form with the ethyl-ene group C atoms deviating by 0.472 (5) and -0.248 (6) Å from the plane defined by the remaining ring atoms.

SUBMITTER: Tafeenko VA

PROVIDER: S-EPMC3089285 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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rac-12,14-Dicyclo-propyl-5,8,13,18,21-penta-oxapenta-cyclo-[13.8.0.0.0.0]tricosa-1(15),2(11),3,9(10),16,22(23)-hexa-ene.

Tafeenko Viktor A VA Aslanov Leonid A LA Puretskiy Nikolay A NA Fedotov Aleksander N AN Mochalov Sergei S SS

Acta crystallographica. Section E, Structure reports online 20110422 Pt 5

The mol-ecule of the title compound, C(24)H(24)O(5), has crystallographic twofold symmetry, with the central O atom lying on the rotation axis. The dihedral angle between the best planes of the benzene rings fused to the oxepine fragment is 38.5 (1)°. The dioxine ring adopts a twist form with the ethyl-ene group C atoms deviating by 0.472 (5) and -0.248 (6) Å from the plane defined by the remaining ring atoms. ...[more]

PMID: 21754483

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