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A Formal Total Synthesis of (-)-Brevisamide.

ABSTRACT: A formal total synthesis of (-)-brevisamide has been achieved. The synthetic approach highlights a chemoselective asymmetric dihydroxylation and a one-pot Fraser-Reid epoxidation/PMB protection reaction sequence.

SUBMITTER: Smith AB 

PROVIDER: S-EPMC3092486 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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A Formal Total Synthesis of (-)-Brevisamide.

Smith Amos B AB   Kutsumura Noriki N   Potuzak Justin J  

Tetrahedron letters 20110401 17

A formal total synthesis of (-)-brevisamide has been achieved. The synthetic approach highlights a chemoselective asymmetric dihydroxylation and a one-pot Fraser-Reid epoxidation/PMB protection reaction sequence. ...[more]

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