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A second polymorph of catena-poly[[(1,10-phenanthroline-κN,N')copper(II)]-di-μ-thio-cyanato-κN:S;κS:N].

ABSTRACT: In the title coordination polymer, [Cu(NCS)(2)(C(12)H(8)N(2))](n), the Cu(II) atom is situated on a twofold rotation axis and is coordinated by two N atoms from the bidentate 1,10-phenanthroline ligand and four thio-cyanate groups to confer a CuN(4)S(2) octa-hedral geometry and resulting in a layer structure extending parallel to (100).

SUBMITTER: Zhang SS 

PROVIDER: S-EPMC3099897 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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A second polymorph of catena-poly[[(1,10-phenanthroline-κN,N')copper(II)]-di-μ-thio-cyanato-κN:S;κS:N].

Zhang Shi-Shen SS   Chen Li-Jiang LJ   Han Yi-Feng YF  

Acta crystallographica. Section E, Structure reports online 20110305 Pt 4

In the title coordination polymer, [Cu(NCS)(2)(C(12)H(8)N(2))](n), the Cu(II) atom is situated on a twofold rotation axis and is coordinated by two N atoms from the bidentate 1,10-phenanthroline ligand and four thio-cyanate groups to confer a CuN(4)S(2) octa-hedral geometry and resulting in a layer structure extending parallel to (100). ...[more]

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