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Bis(N,N,N-trimethyl-ethanaminium) bis-(1,4-tetra-selenido-?Se,Se)cadmate.

ABSTRACT: The title compound, (EtMe(3)N)(2)[Cd(Se(4))(2)], which has been prepared by reaction of CdI(2), K(2)Se(4) and EtMe(3)NI in dimethyl-formamide, is the first example of a [Cd(Se(4))(2)](2-) anion stabilized by alkyl-ammonium counter-ions. The Cd atom in the complex [Cd(Se(4))(2)](2-) anion is tetra-hedrally coordinated by two chelating tetra-selenide ligands, and both CdSe(4) rings exhibit an envelope conformation.

SUBMITTER: Kim J

PROVIDER: S-EPMC3100066 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Bis(N,N,N-trimethyl-ethanaminium) bis-(1,4-tetra-selenido-κSe,Se)cadmate.

Kim Jaemyeong J Kim Kang-Woo KW

Acta crystallographica. Section E, Structure reports online 20110302 Pt 4

The title compound, (EtMe(3)N)(2)[Cd(Se(4))(2)], which has been prepared by reaction of CdI(2), K(2)Se(4) and EtMe(3)NI in dimethyl-formamide, is the first example of a [Cd(Se(4))(2)](2-) anion stabilized by alkyl-ammonium counter-ions. The Cd atom in the complex [Cd(Se(4))(2)](2-) anion is tetra-hedrally coordinated by two chelating tetra-selenide ligands, and both CdSe(4) rings exhibit an envelope conformation. ...[more]

PMID: 21753930

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