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Poly[(?(2)-nitrato-?O:O')(?(2)-pyrimidin-ium-2-carboxyl-ato-?O:O')lithium(I)].

ABSTRACT: In the structure of the title compound, [Li(C(5)H(4)N(2)O(2))(NO(3))](n), the Li(I) ion is coordinated by two carboxyl-ate O atoms donated by two ligands and two nitrate O atoms in a distorted tetrahedral geometry. Li(I) ions, bridged by carboxyl-ate O atoms, form mol-ecular ribbons composed of dimeric units. Two nitrate O atoms link the ribbons into mol-ecular layers parallel to (001). Hydrogen bonds are active between protonated heterocyclic N atoms as donors and carboxyl-ate O atoms as acceptors. The layers are held together by van der Waals inter-actions.

SUBMITTER: Starosta W

PROVIDER: S-EPMC3120533 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Poly[(μ(2)-nitrato-κO:O')(μ(2)-pyrimidin-ium-2-carboxyl-ato-κO:O')lithium(I)].

Starosta Wojciech W Leciejewicz Janusz J

Acta crystallographica. Section E, Structure reports online 20110528 Pt 6

In the structure of the title compound, [Li(C(5)H(4)N(2)O(2))(NO(3))](n), the Li(I) ion is coordinated by two carboxyl-ate O atoms donated by two ligands and two nitrate O atoms in a distorted tetrahedral geometry. Li(I) ions, bridged by carboxyl-ate O atoms, form mol-ecular ribbons composed of dimeric units. Two nitrate O atoms link the ribbons into mol-ecular layers parallel to (001). Hydrogen bonds are active between protonated heterocyclic N atoms as donors and carboxyl-ate O atoms as accept ...[more]

PMID: 21754689

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