Application of the superarmed glycosyl donor to chemoselective oligosaccharide synthesis.

ABSTRACT: Recently, we discovered a novel method for "superarming" glycosyl donors. Herein, this concept has been exemplified in one-pot oligosaccharide syntheses, whereby the superarmed glycosyl donor was chemoselectively activated over traditional "armed" and disarmed glycosyl acceptors. Direct side-by-side comparison of the reactivities of the classic armed and superarmed glycosyl donors further validates the credibility of the novel concept.

SUBMITTER: Mydock LK 

PROVIDER: S-EPMC3150464 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature