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Stereoselective borylative ketone-diene coupling.


ABSTRACT: In the presence of catalytic Ni(cod)(2) and P(t-Bu)(3), ketones, dienes, and B(2)(pin)(2) undergo a stereoselective multicomponent coupling reaction. Upon oxidation, the reaction furnishes 1,3-diols as the major reaction product.

SUBMITTER: Cho HY 

PROVIDER: S-EPMC3195430 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature