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Bis[3,5-difluoro-2-(4-methyl-pyridin-2-yl)phenyl-κC,N](picolinato-κN,O)iridium(III) chloro-form monosolvate.

ABSTRACT: In the title complex, [Ir(C(12)H(8)F(2)N)(2)(C(6)H(4)NO(2))]·CHCl(3), two similar mol-ecules of each component comprise the asymmetric unit. The independent complex mol-ecules are linked by inter-molecular π-π inter-actions [centroid-centroid distance = 3.830 (4) Å]. The Ir(III) ion adopts a distorted octa-hedral geometry, being coordinated by three N atoms, two C atoms, and one O atom of three bidentate ligands, with the N atoms arranged meridionally.

SUBMITTER: Kim YI

PROVIDER: S-EPMC3200786 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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Bis[3,5-difluoro-2-(4-methyl-pyridin-2-yl)phenyl-κC,N](picolinato-κN,O)iridium(III) chloro-form monosolvate.

Kim Young-Inn YI Seo Hoe-Joo HJ Yun Seong-Jae SJ Song Young-Kwang YK Kim In-Chan IC Kang Sung Kwon SK

Acta crystallographica. Section E, Structure reports online 20110806 Pt 9

In the title complex, [Ir(C(12)H(8)F(2)N)(2)(C(6)H(4)NO(2))]·CHCl(3), two similar mol-ecules of each component comprise the asymmetric unit. The independent complex mol-ecules are linked by inter-molecular π-π inter-actions [centroid-centroid distance = 3.830 (4) Å]. The Ir(III) ion adopts a distorted octa-hedral geometry, being coordinated by three N atoms, two C atoms, and one O atom of three bidentate ligands, with the N atoms arranged meridionally. ...[more]

PMID: 22065292

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