Unknown

Dataset Information

0

Chloridodiphen-yl{[1-(1,3-thia-zol-2-yl-κN)ethyl-idene]-4-phenyl-thio-semicarbazidato-κN,S}tin(IV) methanol monosolvate.

ABSTRACT: The title compound, [Sn(C(6)H(5))(2)(C(12)H(11)N(4)S(2))Cl]·CH(4)O, is formed during the reaction between 2-acetyl-thia-zole 4-phenyl-thio-semicarbazone (Hacthptsc) and diphenyl-tin(IV) dichloride in methanol. In the crystal structure, the Sn atom exhibits an octa-hedral geometry with the [N(2)S] anionic tridentate thio-semicarbazone ligand having chloride trans to the central N and the two phenyl groups trans to each other. The Sn-Cl distance is 2.5929 (6), Sn-S is 2.4896 (6) and Sn-N to the central N is 2.3220 (16) Å. The MeOH mol-ecules link the Sn complexes into one-dimensional chains via N-H⋯O and O-H⋯Cl hydrogen bonds.

SUBMITTER: Arumugam SR 

PROVIDER: S-EPMC3201461 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Chloridodiphen-yl{[1-(1,3-thia-zol-2-yl-κN)ethyl-idene]-4-phenyl-thio-semicarbazidato-κN,S}tin(IV) methanol monosolvate.

Arumugam Sri Ranjini SR   Dasary Samuel S R SS   Venkatraman Ramaiyer R   Yu Hongtao H   Fronczek Frank R FR  

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

The title compound, [Sn(C(6)H(5))(2)(C(12)H(11)N(4)S(2))Cl]·CH(4)O, is formed during the reaction between 2-acetyl-thia-zole 4-phenyl-thio-semicarbazone (Hacthptsc) and diphenyl-tin(IV) dichloride in methanol. In the crystal structure, the Sn atom exhibits an octa-hedral geometry with the [N(2)S] anionic tridentate thio-semicarbazone ligand having chloride trans to the central N and the two phenyl groups trans to each other. The Sn-Cl distance is 2.5929 (6), Sn-S is 2.4896 (6) and Sn-N to the ce  ...[more]

Similar Datasets

Unknown Iodido{4-phenyl-1-[1-(1,3-thia-zol-2-yl-κN)ethyl-idene]thio-semicarbazidato-κ(2) N',S}{4-phenyl-1-[1-(1,3-thia-zol-2-yl)ethyl-idene]thio-semicarbazide-κS}cadmium(II).
| S-EPMC3647796 | biostudies-literature
Unknown {4-Phenyl-1-[1-(1,3-thia-zol-2-yl)ethyl-idene]-thio-semicarbazidato}{4-phenyl-1-[1-(1,3-thia-zol-2-yl)ethylidene]-thio-semi-carbazide}nickel(II) chloride mono-hydrate.
| S-EPMC2872247 | biostudies-literature
Unknown Chlorido(1-cyclo-pentyl-idene-4-ethyl-thio-semicarbazidato-κN,S)diphenyl-tin(IV).
| S-EPMC2971835 | biostudies-literature
Unknown Dichlorido{4-cyclo-hexyl-1-[1-(2-pyridyl-κN)ethyl-idene]thio-semicarbazidato-κN,S}methyl-tin(IV).
| S-EPMC2979086 | biostudies-literature
Unknown Dichlorido{4-cyclo-hexyl-1-[1-(2-pyridyl-κN)ethyl-idene]thio-semicarbazidato-κN,S}phenyl-tin(IV).
| S-EPMC3011751 | biostudies-literature
Unknown Chlorido[1-(4,5-dihydro-1,3-thia-zol-2-yl-κN)ethanone thio-semicarbazonato-κN,S]nickel(II).
| S-EPMC3050191 | biostudies-literature
Unknown [2-(Biphenyl-4-yl)-1,3-thia-zol-4-yl]methanol.
| S-EPMC3470322 | biostudies-literature
Unknown 1-(5-Nitro-2-oxoindolin-3-yl-idene)-4-o-tolyl-thio-semicarbazide methanol monosolvate.
| S-EPMC2971320 | biostudies-literature
Unknown Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethyl-idene]thio-semicarbazidato-κ(2)N(1),S}cadmium.
| S-EPMC3344363 | biostudies-literature
Unknown N-(1,3-Thia-zol-2-yl)-N'-[(thio-phen-2-yl)carbon-yl]thio-urea hemihydrate.
| S-EPMC3588839 | biostudies-literature