Tert-Butyl N-((1S)-2-hy-droxy-1-{N'-[(E)-2-hy-droxy-4-meth-oxy-benzyl-idene]hydrazinecarbon-yl}eth-yl)carbamate.

ABSTRACT: The mol-ecule of the title compound, C(16)H(23)N(3)O(6), is twisted about the chiral C atom with the dihedral angle formed between the amide residues being 76.9?(3)°. Overall, the mol-ecule is curved with the terminal organic groups lying to the same side. The conformation about the imine bond [1.291?(5)?Å] is E and an intra-molecular O-H?N hydrogen bond generates an S(6) ring. In the crystal, O-H?O and N-H?O hydrogen bonds involving the hy-droxy, amine and carbonyl groups lead to the formation of supra-molecular layers, which stack along the c-axis direction.

SUBMITTER: Wardell JL 

PROVIDER: S-EPMC3212283 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature