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(E)-Methyl N'-[(1H-indol-3-yl)methyl-idene]hydrazinecarboxyl-ate 0.25-hydrate.

ABSTRACT: The asymmetric unit of the title compound, C(11)H(11)N(3)O(2)·0.25H(2)O, contains two independent organic mol-ecules and a water mol-ecule, which lies on a twofold rotation axis. The side chains of the two mol-ecules have slightly different orientations, the C=N-N-C torsion angle being -163.03 (15)° in one and -177.52 (14)° in the other, with each adopting a trans configuration with respect to the C=N bond. In the crystal, mol-ecules are linked into chains extending along b by N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds and in addition, four inter-molecular C-H⋯π inter-actions are present.

SUBMITTER: Lv LP 

PROVIDER: S-EPMC3212339 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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(E)-Methyl N'-[(1H-indol-3-yl)methyl-idene]hydrazinecarboxyl-ate 0.25-hydrate.

Lv Lu-Ping LP   Yu Tie-Ming TM   Yu Wen-Bo WB   Hu Xian-Chao XC  

Acta crystallographica. Section E, Structure reports online 20110709 Pt 8

The asymmetric unit of the title compound, C(11)H(11)N(3)O(2)·0.25H(2)O, contains two independent organic mol-ecules and a water mol-ecule, which lies on a twofold rotation axis. The side chains of the two mol-ecules have slightly different orientations, the C=N-N-C torsion angle being -163.03 (15)° in one and -177.52 (14)° in the other, with each adopting a trans configuration with respect to the C=N bond. In the crystal, mol-ecules are linked into chains extending along b by N-H⋯O, O-H⋯N and O  ...[more]

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