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Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands.

ABSTRACT: Palladium-catalyzed aerobic oxidative cross-couplings of indoles and benzene have been achieved by using 4,5-diazafluorene derivatives as ancillary ligands. Proper choice of the neutral and anionic ligands enables control over the reaction regioselectivity.

SUBMITTER: Campbell AN

PROVIDER: S-EPMC3228523 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands.

Campbell Alison N AN Meyer Eric B EB Stahl Shannon S SS

Chemical communications (Cambridge, England) 20110822 37

Palladium-catalyzed aerobic oxidative cross-couplings of indoles and benzene have been achieved by using 4,5-diazafluorene derivatives as ancillary ligands. Proper choice of the neutral and anionic ligands enables control over the reaction regioselectivity. ...[more]

PMID: 21860880

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