Synthesis and reactivity of bicyclo[3.2.1]octanoid-derived cyclopropanes.

ABSTRACT: Photochemical oxa-di-π-methane rearrangement of bicyclo[3.2.1]octanoid scaffolds affords multifunctional, donor-acceptor cyclopropanes. A related photochemical reaction of an iminium ether substrate uncovered an unprecedented aza-di-π-methane rearrangement of a β,γ-unsaturated iminium. Donor-acceptor cyclopropanes have been evaluated as substrates for reactions generating several new chemotypes.

SUBMITTER: Goodell JR 

PROVIDER: S-EPMC3235415 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature