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Spirodiepoxide-based cascades: direct access to diverse motifs.


ABSTRACT: Allene epoxide formation/opening reaction sequences enabled direct access to diverse products. Described here are a single flask procedure for allene preparation and allene oxidation/derivatization reactions that give, among others, diendiol, diyndiol, α'-hydroxy-γ-enone, dihydrofuranone, butenolide, and δ-lactone products.

SUBMITTER: Sharma R 

PROVIDER: S-EPMC3235951 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature