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Cis-Bis(benzyl-diphenyl-phosphane-?P)dichloridoplatinum(II) dichloro-methane sesquisolvate.

ABSTRACT: The asymmetric unit of the title compound, [PtCl(2)(C(19)H(17)P)(2)](2)·3CH(2)Cl(2), contains two complex mol-ecules and three dichloro-methane solvent mol-ecules, two of which are disordered over various positions. The Pt(II) complexes reveal a slightly distorted square-planar geometry with average Pt-P and Pt-Cl bond lengthss of 2.252?(8) and 2.363?(8)?Å, respectively, and average P-Pt-P and Cl-Pt-Cl angles of 99.17?(8) and 87.1?(7)°, respectively.

SUBMITTER: Davis WL

PROVIDER: S-EPMC3238707 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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cis-Bis(benzyl-diphenyl-phosphane-κP)dichloridoplatinum(II) dichloro-methane sesquisolvate.

Davis Wade L WL Meijboom Reinout R

Acta crystallographica. Section E, Structure reports online 20111123 Pt 12

The asymmetric unit of the title compound, [PtCl(2)(C(19)H(17)P)(2)](2)·3CH(2)Cl(2), contains two complex mol-ecules and three dichloro-methane solvent mol-ecules, two of which are disordered over various positions. The Pt(II) complexes reveal a slightly distorted square-planar geometry with average Pt-P and Pt-Cl bond lengthss of 2.252 (8) and 2.363 (8) Å, respectively, and average P-Pt-P and Cl-Pt-Cl angles of 99.17 (8) and 87.1 (7)°, respectively. ...[more]

PMID: 22199584

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