Browse
Submit Data
Databases
API
Help

Dataset Information

49 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Catena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-?-chlorido-[chloridocopper(II)]-di-?-azido-?N:N]].

ABSTRACT: The crystal structure of the title complex, {(C(2)H(8)N)[CuCl(2)(N(3))]}(n), exhibits inorganic chains consisting of Cu(II) cations as well azide and chloride anions. The chains, made up from Cu-Cl-Cu-N-Cu linkages, are aligned parallel to the c axis. This architecture is further stabilized by a number of N-H?Cl hydrogen bonds involving the protonated charge-compensating dimethyl-amine cations and chloride atoms.

SUBMITTER: Zhang WY

PROVIDER: S-EPMC3238763 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

catena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-μ-chlorido-[chloridocopper(II)]-di-μ-azido-κN:N]].

Zhang Wei-Yi WY Yang Li L Liu Jie J

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

The crystal structure of the title complex, {(C(2)H(8)N)[CuCl(2)(N(3))]}(n), exhibits inorganic chains consisting of Cu(II) cations as well azide and chloride anions. The chains, made up from Cu-Cl-Cu-N-Cu linkages, are aligned parallel to the c axis. This architecture is further stabilized by a number of N-H⋯Cl hydrogen bonds involving the protonated charge-compensating dimethyl-amine cations and chloride atoms. ...[more]

PMID: 22199640

Similar Datasets

catena-Poly[[chloridocopper(II)]bis-(μ-3,3',5,5'-tetra-methyl-4,4'-methylene-dipyrazole)[chloridocopper(II)]-di-μ-chlorido].

Project description:In the title compound, [Cu(2)Cl(4)(C(11)H(16)N(4))](n), the Cu atom is coordinated by two N atoms of two 3,3',5,5'-tetra-methyl-4,4'-methyl-enedipyrazole (H(2)mbdpz) ligands, two bridging Cl atoms and one terminal Cl atom, forming a square-pyramidal geometry. The bridging Cl atoms and the bridging H(2)mbdpz ligands connect the Cu atoms to build up an extended one-dimensional chain. The chains are further connected through N-H⋯Cl hydrogen bonds to build up a two-dimensional layer in the (011) plane. An inversion centre lies between every pair of adjacent Cu atoms.

| S-EPMC2960916 | biostudies-literature

catena-Poly[[bis[quinazolin-4(3H)-one-κN]cadmium(II)]-di-μ-chlorido].

Project description:The asymmetric unit of the title compound, [CdCl(2)(C(8)H(6)N(2)O)(2)](n), consists of one mol-ecule of the 3H-quinazolin-4-one ligand, one Cd(2+) cation, which is located on a twofold axis, and one chlorido ligand in a general position. The latter bridges metal cations, forming a one-dimensional polymer along the b axis. The Cd⋯Cd distance along the chain is 3.7309 (7) Å. The octa-hedral coordination around the metal is completed by two ligands in a trans axial geometry which coordinate through the N atom in 1 position. Moderately strong classical N-H⋯O hydrogen bonds around crystallographic inversion centers cross-link adjacent polymeric chains.

| S-EPMC3009324 | biostudies-literature

catena-Poly[[trans-bis-(1,3-benzo-thia-zole-κN)manganese(II)]-di-μ-chlorido].

Project description:In the title coordination polymer, [MnCl2(C7H5NS)2] n , the Mn(II) ion is located on the inter-section of a twofold rotation axis and a mirror plane and adopts an octa-hedral coordination geometry defined by two mutually trans N atoms from benzo-thia-zole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites. The Mn(II) ions are connected by two bridging Cl atoms, forming chains parallel to the c axis. The crystal packing can be descibed as alternating layers parallel to (001) featuring π-π stacking inter-actions with a centroid-centroid distance of 3.6029 (15) Å.

| S-EPMC4120608 | biostudies-literature

catena-Poly[[(liriodenine-κN,O)lead(II)]-di-μ-chlorido].

Project description:The title compound, [PbCl(2)(C(17)H(9)NO(3))](n), was synthesized by the hydro-thermal reaction of PbCl(2) and liriodenine. The lead(II) atom has a distorted octa-hedral environment made up of the O and N atoms of the liriodenine ligand [Pb-O 2.666 (4) Å, Pb-N 2.587 (5) Å, O-Pb-N 61.78 (14)°] and four bridging chloro ligands, which link the complex mol-ecules into infinite chains along the a axis. Both crystallographically independent chloro-bridges are asymmetric, so that the Pb atom participates in two short [2.6872 (18) and 2.7952 (18) Å] and two noticeably longer Pb-Cl bonds [2.9626 (18) and 3.031 (2) Å].

| S-EPMC2980232 | biostudies-literature

catena-Poly[[bis-(pyridine-3-carb-oxy-lic acid-κN)mercury(II)]-di-μ-chlorido].

Project description:In the title compound, [HgCl(2)(C(6)H(5)NO(2))(2)](n), the Hg(II) cation is located on an inversion center and is six-coordinated in a distorted octa-hedral geometry by two N atoms from two pyridine-3-carb-oxy-lic acid mol-ecules and four bridging Cl(-) anions. The bridging function of the Cl(-) anions leads to polymeric chains running along the a axis. One Hg-Cl bond is much longer than the other. In the crystal, O-H⋯O and weak C-H⋯Cl hydrogen bonds are observed.

| S-EPMC3343898 | biostudies-literature

catena-Poly[cadmium(II)-μ-benzene-1,2-diamine-κN:N'-di-μ-chlorido].

Project description:The title compound, [CdCl(2)(C(6)H(8)N(2))](n), is a coordination polymer prepared by the hydro-thermal reaction of cadmium chloride and o-diamino-benzene. The cadmium cation, located on an inversion center, is octa-hedrally coordinated by four Cl atoms at equatorial sites and two N atoms from two ligands at the axial sites. Cd atoms are bridged by Cl atoms, forming extended chains parallel to [010]. Neighboring chains are connected by N-H⋯Cl hydrogen bonds.

| S-EPMC2959288 | biostudies-literature

catena-Poly[(dichloridocadmium)-di-μ-chlorido-[bis-(morpholinium-κO)cadmium]-di-μ-chlorido].

Project description:In the title compound, [Cd(2)Cl(6)(C(4)H(10)NO)(2)](n), the coordination geometry of each Cd(II) ion is distorted octa-hedral, but with quite different coordination environments. One Cd(II) atom is coordinated by four Cl atoms and two O atoms from two morpholinium ligands, while the other is coordinated by six Cl atoms. Adjacent Cd(II) atoms are inter-connected alternately by paired chloride bridges, generating a chain parallel to the a axis. Inter-chain N-H⋯Cl inter-actions form a two-dimensional network.

| S-EPMC3212201 | biostudies-literature

catena-Poly[[chloridomercury(II)]-μ-1,4-diaza-bicyclo-[2.2.2]octane-κN:N'-[chlorido-mercury(II)]-di-μ-chlorido].

Project description:In the title coordination polymer, [Hg(2)Cl(4)(C(6)H(12)N(2))](n), each Hg(II) center within the chain is four-coordinated by one terminal Cl atom, two bridging μ(2)-Cl atoms, and one N-atom donor from a μ(2)-1,4-diaza-bicyclo-[2.2.2]octane (μ(2)-daco) ligand in a distorted tetra-hedral geometry. The daco ligand acts as an end-to-end bridging ligand and bridges adjacent Hg(II) centers, forming a chain running along [001]. Weak C-H⋯Cl hydrogen-bonding inter-actions link the chains into a three-dimensional network. Comparison of the structural differences with previous findings suggests that the space between the two N donors, as well as the skeletal rigidity in N-heterocyclic linear ligands, may play an important role in the construction of such supra-molecular networks.

| S-EPMC2971285 | biostudies-literature

catena-Poly[[(1,10-phenanthroline-κN,N')lead(II)]-μ-azido-κN:N-μ-nitrito-κO,O':O'-[(1,10-phenanthroline-κN,N')lead(II)]-di-μ-azido-κN:N].

Project description:The title coordination polymer, [Pb(2)(N(3))(3)(NO(2))(C(12)H(8)N(2))(2)](n), has as the repeat unit a centrosymmetric dinuclear mol-ecule having azide and nitrite groups that bridge adjacent heterocycle-coordinated metal centers. One of the azide group uses its terminal ends to bridge whereas the nitrite group chelates to one metal atom and uses one of its O atoms to bridge. The azide and nitrite groups are disordered with respect to each other in a 1:1 ratio. Adjacent dinuclear mol-ecules are further bridged by the other two azide groups, generating a linear chain motif parallel to [010]. Half of the Pb atoms show a Ψ-dodeca-hedral coordination and the other half show a Ψ-penta-gonal-bipyramidal coordination.

| S-EPMC3006727 | biostudies-literature

catena-Poly[[bis-(pyrazine-2-carbox-amide)mercury(II)]-di-μ-chlorido].

Project description:In the polymeric title compound, [HgCl(2)(C(5)H(5)N(3)O)(2)](n), the Hg(II) atom (site symmetry ) adopts a distorted trans-HgN(2)Cl(4) octa-hedral coordination geometry. In the crystal, adjacent mercury ions are bridged by pairs of chloride ions, generating infinite [100] chains, and N-H⋯O and N-H⋯(N,N) hydrogen bonds help to consolidate the packing.

| S-EPMC2983533 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data