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2-[(Pyridin-3-yl-amino)-meth-yl]phenol.

ABSTRACT: In the title compound, C(12)H(12)N(2)O, the aromatic rings at either ends of the -CH(2)-NH- link are twisted by 68.79 (7)°. In the crystal, the hy-droxy substituent is a hydrogen-bond donor to the N atom of the pyridine ring of an adjacent mol-ecule, and the hydrogen bond generates a chain along the b axis; it is also a hydrogen-bond acceptor to the amino group of another adjacent mol-ecule. The two hydrogen bonds lead to the formation of a layer structure.

SUBMITTER: Xu J

PROVIDER: S-EPMC3238919 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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2-[(Pyridin-3-yl-amino)-meth-yl]phenol.

Xu Jing J Gao Shan S Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20111112 Pt 12

In the title compound, C(12)H(12)N(2)O, the aromatic rings at either ends of the -CH(2)-NH- link are twisted by 68.79 (7)°. In the crystal, the hy-droxy substituent is a hydrogen-bond donor to the N atom of the pyridine ring of an adjacent mol-ecule, and the hydrogen bond generates a chain along the b axis; it is also a hydrogen-bond acceptor to the amino group of another adjacent mol-ecule. The two hydrogen bonds lead to the formation of a layer structure. ...[more]

PMID: 22199768

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2-{[(Pyridin-2-yl)amino]-meth-yl}phenol.

Project description:The planes of the aromatic rings of the title compound, C(12)H(12)N(2)O, are twisted by 50.33 (15)°. The phenol O atom is a hydrogen-bond donor to the pyridine N atom, resulting in the formation of an eight-membered ring in the mol-ecule. The amino N atom is a hydrogen-bond donor to the phenol O atom of an adjacent mol-ecule; this hydrogen bond leads to the formation of a helical chain that runs along the a axis.

| S-EPMC3414928 | biostudies-literature

(E)-2-{[(2-Amino-pyridin-3-yl)imino]-meth-yl}-4,6-di-tert-butyl-phenol.

Project description:In the title compound, C(20)H(27)N(3)O, the hy-droxy group forms an intra-molecular O-H⋯N hydrogen bond with the imino N atom. The dihedral angle between the aromatic rings is 33.09 (9)°. In the crystal, mol-ecules form centrosymmetric dimers via pairs of N-H⋯N hydrogen bonds involving amino-pyridine fragments.

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Project description:In the title compound, C19H15N3O, the benzimidazole ring system makes dihedral angles of 44.36 (7) and 75.67 (7)° with the pyridine and benzene rings, respectively. In the crystal, phenolic O-H⋯N hydrogen bonds to benzimidazole N-atom acceptors give rise to a chain extending along [011].

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2-Fluoro-6-[(E)-(pyridin-2-yl)imino-meth-yl]phenol.

Project description:The title compound, C(12)H(9)FN(2)O, is almost planar (r.m.s. deviation for the 16 non-H atoms = 0.019?Å), a conformation stabilized by an intra-molecular O-H?N hydrogen bond, which generates an S(6) ring. In the crystal, inversion dimers linked by pairs of C-H?O hydrogen bonds generate R(2) (2)(16) loops.

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4-Bromo-2-{[(pyridin-3-ylmeth-yl)imino]-meth-yl}phenol.

Project description:The title compound, C(13)H(11)BrN(2)O, is a polydentate Schiff base and reveals intra-molecular O-H⋯N hydrogen bonding between the hy-droxy O atom and the imino N atom. The dihedral angle between the aromatic ring and the pyridyl ring is 71.7 (1)°. In the crystal, the mol-ecules are stacked in columns along the c axis and several inter-molecular π-π inter-actions are present between the six-membered rings, with a shortest centroid-centroid distance of 3.707 (2) Å.

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2-[(Adamantan-1-yl-amino)-meth-yl]phenol.

Project description:The asymmetric unit of the title compound, C(17)H(23)NO, contains two independent mol-ecules. In both mol-ecules, the hy-droxy group is involved in the formation of an intra-molecular O-H⋯N hydrogen bond. In the crystal, there are two crystallographically independent chains of the mol-ecules propagating along the c axis and formed by weak inter-molecular N-H⋯O hydrogen bonds.

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2-[(Pyrimidin-2-yl-amino)-meth-yl]phenol.

Project description:In the title compound, C(11)H(11)N(3)O, the aromatic rings at either ends of the -CH(2)-NH- link are twisted by 72.58 (8)°; the hy-droxy substituent is a hydrogen-bond donor to an N atom of the pyrimidine ring. The other N atom of the pyrimidine ring is a hydrogen-bond acceptor to the amino group of an inversion-related mol-ecule.

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2-{[(Pyrazin-2-yl)amino]-meth-yl}phenol.

Project description:The two aromatic rings of the title compound, C(11)H(11)N(3)O, are nearly perpendicular to one another, with a dihedral angle between their planes of 80.52 (18)°. In the crystal, the amino N atom is a hydrogen-bond donor to the pyrazine N(1) atom of an inversion-related mol-ecule and the hy-droxy O atom is a hydrogen-bond donor to the pyrazine N(4) atom of another mol-ecule. The two hydrogen bonds lead to the formation of a helical chain that runs along the b axis.

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2-Eth-oxy-6-[(3-methyl-pyridin-2-yl)-imino-meth-yl]phenol.

Project description:The title Schiff base compound, C(15)H(16)N(2)O(2), was prepared by the condensation reaction of equimolar quanti-ties of 3-eth-oxy-salicyl-aldehyde with 2-amino-3-methyl-pyridine in methanol. The dihedral angle between the benzene ring and the pyridine ring is 2.6 (2)° and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring.

| S-EPMC3089178 | biostudies-literature

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