Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

5-Chloro-2-(phenyl-diazen-yl)pyridine.

ABSTRACT: In the title compound, C(11)H(8)ClN(3), the azo group adopts a trans conformation and the dihedral angle between the six-membered rings is 15.47 (8)°.

SUBMITTER: Thies S

PROVIDER: S-EPMC3238951 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

5-Chloro-2-(phenyl-diazen-yl)pyridine.

Thies Steffen S Näther Christian C Herges Rainer R

Acta crystallographica. Section E, Structure reports online 20111112 Pt 12

In the title compound, C(11)H(8)ClN(3), the azo group adopts a trans conformation and the dihedral angle between the six-membered rings is 15.47 (8)°. ...[more]

PMID: 22199800

Similar Datasets

3-(4-Chloro-phenyl-diazen-yl)-1-methyl-1,4,5,6-tetra-hydro-pyridine.

Project description:The title compound, C(12)H(14)ClN(3), represents the planar azoenamine tautomer. The benzene ring forms a dihedral angle of 2.5 (1)° with the azoenamine group. Electron delocalization is indicated by the values of the bond lengths in the chain. The tetra-hydro-pyridine ring adopts a half-chair conformation and the dihedral angle between the least-squares plane defined by the five coplanar C atoms and the azoenamine unit is 2.0 (1)°, while the envelope-flap C atom lies out of this plane by 0.579 (2) Å. The mol-ecular packing is governed by van der Waals inter-actions through the stacking of adjacent mol-ecules, resulting in a two-dimensional sheet structure.

| S-EPMC2961736 | biostudies-literature

Chlorido{5-chloro-2-[2-(methyl-sulfanyl)phenyl-diazen-yl]phenyl}-platinum(II).

Project description:The title compound, [Pt(C(13)H(10)ClN(2)S)Cl], contains a Pt atom tetra-coordinated by a benzene C, a diazene N, a Cl and an S atom in an approximately square-planar geometry. The mol-ecules dimerize through a nonbonded S⋯S inter-action [S⋯S = 3.523 (18) Å]. There are no hydrogen bonds and the crystal packing is stabilized by four inter-molecular π-π inter-actions; the centroid-centroid distances are 3.804 (3), 3.638 (3), 3.804 (3) and 3.638 (3) Å, and the corresponding perpendicular distances are 3.369, 3.448, 3.406 and 3.466 Å.

| S-EPMC2960293 | biostudies-literature

Crystal structure of di-chlorido-bis-[2-(phenyl-diazen-yl)pyridine-κN (1)]zinc.

Project description:The structure of the title complex, [ZnCl2(C11H9N3)2], comprises two 2-(phenyl-diazen-yl)pyridine ligands coordin-ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra-hedral geometry. The complex exhibits twofold rotation symmetry, with the rotation axis bis-ecting the zinc cation. The structure is stabilized by weak inter-molecular C-H⋯Cl inter-actions [C⋯Cl = 3.411 (2) and 3.675 (2) Å], connecting neighbouring mol-ecules into layers perpendicular to the c axis.

| S-EPMC4645076 | biostudies-literature

5-(Phenyl-diazen-yl)tropolone.

Project description:THE TITLE COMPOUND [SYSTEMATIC NAME: (E)-2-hy-droxy-5-(phenyl-diazen-yl)cyclo-hepta-2,4,6-trien-1-one], C(13)H(10)N(2)O(2), is essentially planar with an r.m.s. deviation of 0.036 (2) Å and a dihedral angle of 1.57 (8)° between the phenyl and tropolone rings. In the crystal, mol-ecules are linked by pairs of O-H⋯O hydrogen bonds into inversion dimers. The dimers are further connected by C-H⋯O hydrogen bonds and π-π stacking inter-actions, with centroid-centroid distances of 3.6934 (9) and 3.6282 (9) Å.

| S-EPMC3343922 | biostudies-literature

4-(4-Hydroxy-phenyl-diazen-yl)-benzonitrile.

Project description:The molecule of the title compound, C(13)H(9)N(3)O, is achiral but forms a chiral arrangement in the crystal structure. The mol-ecule adopts an E configuration with respect to the N=N bond and is almost planar, with an r.m.s. deviation of 0.0439?Å from the plane through all atoms in the mol-ecule. The dihedral angle between the two benzene rings is 2.2?(2)°. In the crystal structure, inter-molecular O-H?N hydrogen bonding generates a chain.

| S-EPMC2960800 | biostudies-other

[2-(Phenyl-diazen-yl)pyrrolato]bis(2-pyridylphen-yl)iridium(III).

Project description:In the title compound, [Ir(C(10)H(8)N(3))(C(11)H(8)N)(2)], the Ir center is octa-hedrally coordinated by the three chelating ligands, with two cyclo-metalated 2-pyridylphenyl ligands [Ir-N = 2.049?(5) and 2.030?(5)?Å; Ir-C = 2.016?(6) and 2.012?(6)?Å] and a bidentate 2-(phenyl-diazen-yl)pyrrolate ligand [Ir-N = 2.204?(5) and 2.079?(5)?Å]. The Ir-N(diazen-yl) bond is longer than the Ir-N(pyrrolate) bond. The structure is stabilized by aromatic ?-? stacking, the shortest parallel distance between ring centroids being 3.426?(8)?Å..

| S-EPMC2960816 | biostudies-other

4-(4-Ethyl-phenyl-diazen-yl)phenol.

Project description:The crystal structure of the title compound, C(14)H(14)N(2)O, determined at 100 K, shows that the mol-ecules are not planar in the solid state, in contrast to other diazene (azobenzene) derivatives. The dihedral angle between the planes of the two aromatic rings is 42.32 (7)°. The mol-ecules are linked by inter-molecular O-H⋯N hydrogen bonds, forming an infinite one-dimensional chain.

| S-EPMC2961569 | biostudies-literature

4-Chloro-1-(4-methyl-phenyl-sulfon-yl)-1H-pyrrolo[2,3-b]pyridine.

Project description:The crystal structure of the title compound, C(14)H(11)ClN(2)O(2)S, features a three-dimensional network stabilized by π-π inter-actions between the rings of the 4-methyl-phenyl-sulfonyl protecting group [centroid-centroid distance = 3.623 (1) Å]. The 4-methyl-phenyl-sulfonyl ring makes a dihedral angle of 79.60 (6)° with the 4-chloro-1H-pyrrolo[2,3-b]pyridine unit.

| S-EPMC2972132 | biostudies-literature

2,4,6-Trinitro-N-[4-(phenyl-diazen-yl)phen-yl]aniline.

Project description:The title compound, C(18)H(12)N(6)O(6), was prepared from the reaction of 4-(phenyl-diazen-yl)aniline (aniline yellow) with picryl-sulfonic acid. The dihedral angle formed by the two benzene rings of the diphenyl-diazenyl ring system is 6.55 (13)° and that formed by the rings of the picrate-aniline ring system is 48.76 (12)°. The mol-ecule contains an intra-molecular aniline-nitro N-H⋯O hydrogen bond.

| S-EPMC3099790 | biostudies-literature

3-Phenyl-diazen-yl-1,2-dimethyl-1H-indole.

Project description:In the title mol-ecule, C(16)H(15)N(3), the indole ring system is planar within 0.021 (3) Å and the phenyl ring is inclined to this plane by 17.32 (14)°. π-π contacts involving the pyrrole rings of inversion-related indole units [centroid-centroid distance = 3.5187 (17) Å] stabilize the crystal structure.

| S-EPMC3008000 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data