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1,1'-Binaphthyl-2,2'-diyl benzyl-phos-phoramidate.

ABSTRACT: In the title compound, C(27)H(20)NO(3)P, the P atom exhibits a somewhat distorted PNO(3) tetra-hedral geometry, with the O-P-O angle for the binaphthyl fragment being 102.82 (6)°. The dihedral angle between the naphthyl ring systems is 59.00 (2)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R(2) (2)(8) loops.

SUBMITTER: Gowda RR

PROVIDER: S-EPMC3238962 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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1,1'-Binaphthyl-2,2'-diyl benzyl-phos-phoramidate.

Gowda Ravikumar R RR Ramkumar Venkatachalam V Chakraborty Debashis D

Acta crystallographica. Section E, Structure reports online 20111116 Pt 12

In the title compound, C(27)H(20)NO(3)P, the P atom exhibits a somewhat distorted PNO(3) tetra-hedral geometry, with the O-P-O angle for the binaphthyl fragment being 102.82 (6)°. The dihedral angle between the naphthyl ring systems is 59.00 (2)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R(2) (2)(8) loops. ...[more]

PMID: 22199811

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